A never-before-seen photo of Angelina Jolie is set to hit the auction block at Christie's next month in London.

The provocative photo was taken by fashion photographer David LaChapelle and features Jolie, 37, posing topless with a white horse close to her chest.

The carefree photo of Jolie at age 25 was an outtake from 2001 Rolling Stone magazine shoot. According to the Daily Mail, the sultry image could rake in up to $53,000.

Visible on her left arm in the shot is the now infamous tattoo of the name of her ex-husband, actor Billy Bob Thornton. The couple's three-year relationship was a media spectacle, and after it ended Jolie had the tattoo removed.

The LaChapelle image will go on sale alongside a black and white print of Angelina and Brad Pitt posing as husband and wife for Steven Klein in 2005, after they worked on "Mr. & Mrs. Smith," and before they were officially together.